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91
Colloidal Silver Production / Re: maltrodextrin powder
« Last post by Gene on March 20, 2024, 05:53:43 AM »
The higher the DE number the better a stabilizer the malto is BUT the worse it gets as a reducer. Reason being, a DE of 12 is 12 glucose molecules with the head end of one hanging onto the tail end of the next, rinse and repeat where only one "head" at one end of that long chain can reduce ONE silver oxide particle to Colloidal Silver. The higher the DE number the more malto you need to reduce a given weight of silver oxide dissolved in water.

The good side of a higher DE number is that the DE becomes a much better stabilizer for non-gelcapped Colloidal Silver production because the DE chains are longer where after reduction, the spent malto reducer crowds the silver particles and coats them, thereby stabilizing them where the more "stuff" they're coated with, the better they're stabilized. Makes sense, right?  If you dip something in really thin paint, after its dry its easy to scratch it. If you dip it in much thicker paint, after its dry its that much harder to scratch it as an analogy.

I have a friend in Austria (Vienna) who makes Colloidal Silver. I believe he bought some DE though I don't recall which DE number he chose.

If I had to choose, I'd probably go middle of the road. 12 should work as a good stabilizer also. Remember, the higher the DE number the more malto you need to do the same reduction than a lower DE number malto requires. Its all a balancing act.

IIRC, the individual that came up with the formula to compute how much malto you need figured it out based on a worst case - all highest DE number malto so if you get DE 12 and use that formula you will have an excess of malto in solution which will work out to your advantage to speed up reduction and also provide even more stabilization when thats necessary (non-gelcapped Colloidal Silver).
92
Colloidal Silver Production / Re: availability of Soda and capping agents
« Last post by Gene on March 20, 2024, 05:39:00 AM »
Glucose syrup (which is NOT light clear corn syrup) has fructose in it. The only place I've seen that I can get it is a beer/winemaking supply shop.  IIRC, it has a DE equivalency of around 2 or 3.  Looking online, there are different formulations so its probably not a good thing to use to reduce with.  I have seen it in person. Its kind of a clear, thick syrup.

If you can't get clear corn syrup, maltodextrin works just as well. The only downsides are the need to use substantially more (which hurts nothing) to reduce properly and some people perceive a "taste" from maltodextrin they don't care for. I don't taste it though. Also, for the higher concentration of it in solution because of the longer chain molecules, it will produce a slightly darker result at the same PPM as other reducers. Its not significant but enough its noticeable.  If you use it and you're not sure, simply dilute a little of your result (if its over 20PPM) to 20PPM concentration and look at the color. If its slightly darker yellow than what you're used to, you're good to go.

Straight glucose powder (dextrose in food use) works too but its a little touchy given you need so little. Some have used it to great success. I bought a pound from the beer/winemaking shop when I bought a pound of malto also and I did try the glucose to reduce with but every time, I got a somewhat cloudy result. I never figured out why so I abandoned using it.  I do recall someone else here who tried glucose powder had a similar problem they never figured out either.

There was something called golden syrup somebody here was using which seemed to work for them but I've now stated my total knowledge on the subject (wink).

There are other reducing agents you could use including cinnamon extract (instructions on how to make this are in the Kephra's notebook section in one of the top pinned articles).

Another alternative is to make invert sugar. Information on how to do this is also in the Kephra's notebook section.  Basically its table sugar syrup (what they call invert syrup). This purportedly works well to reduce with also though I've never had the inkling to try it.

All you need to do if you're making higher PPM Colloidal Silver is to process at about 150F (hotplate with a good temperature control works just fine). You don't need special glassware (I use a 1 quart mason jar to great success).

When you turn on your power supply that feeds the current limiter which is connected to your cell, the current should IMMEDIATELY be whatever the current setpoint is. NOTHING "ramps". Aside from adjusting the current setpoint, the only other adjustment you can make is raising or lowering the cathode in the cell to change the cell voltage.

No magic, not rocket science. Some things may not be obvious but they're easy to figure out (or you can ask us if you're stumped).

What you've encountered with all the confusing information from all over the place is the same crap we all have early on... and then we found this site and learned the truth and realized that most "experts" don't know their arse from their elbow but for sure they keep telling you they do very convincingly(sigh).

Companies that make commercial Colloidal Silver equipment are in the business of making money and sadly many of these companies are scams that charge a lot of money for something you can build better yourself for a couple dollars.

As they say, caveat emptor (let the buyer beware).  ...Only YOU can protect YOU (sad but true).
93
Colloidal Silver Production / Re: availability of Soda and capping agents
« Last post by kephra on March 19, 2024, 09:47:24 PM »
...
Maybe I should briefly describe the local state of the art. This may be of interest for you.
You run with either 5 or 10 mA . Don´t know which and when. Heat pure DW to the boiling point but then no more. If possible, brew in a double walled glas to keep the heat. There is a magic ppm formula but this falls flat, because it assumes full current. Unfortunately current rises slowly until the current reduction kicks in, which may take several minutes. Sometimes cut-off is never reached even after hours. No stirring, no additives. There is some who use pulsed dc (a la zapper), some single polarity (which sometimes produces a yellow result), some switching polarity. It is left totally unclear which is better. Devices go up to 60V (which is the maximum allowable voltage for home use) to get things going at all. Single polarity produces black or grey sludge on the anode. Some devices use a cathode different than silver, but in this case it is not a bad thing to stay with both silver because people are bound to switch to alternating polarity without taking care of that.
....
Thats not the state of the art, its more the state of ignorance.  The plethora of disinformation simply astounds me.

Its normal for the anode to turn black.  Its just silver oxide, and is easily converted back into pure elemental silver just by heating it up in a blue flame until the black turns white.

Without the sodium carbonate in the water, the silver that comes off the anode just plates onto the cathode as sludge.  The sodium carbonate stops that and keeps the silver in solution.  The corn syrup, or other glucose based sugars convert silver ions into silver metal which forms the nanoparticles, and also stabilizes their size.  The end result is silver nanoparticles suspended in alkaline water.  Just about all the initial lab testing which showed silver nanoparticles were an effective antibiotic used silver reduced with glucose. 

By the way, corn syrup is glucose and maltose.  There is no fructose in corn syrup unless it was added to it, then it is called high fructose corn syrup.  Fructose can be made from corn starch but it is a different process. 

You asked about maltodextrin. The DE number is the number of glucose molecules in the chain.  Maltodextrin is chains of 3 to 17 glucose molecules (some sources say 20 molecules).  Above that is dextrin and starch.  Lower DE numbers are better reducing agents, and higher DE numbers are better stabilizers due to their bigger molecular size.

As a reducing agent, maltodextrin has only 1 active binding site, so for DE 3, it takes 3 times as much to reduce silver as the weight of pure glucose would.  The good thing is that while there is a bottom limit to how much you need, there is no upper limit.  So its best to use more.  For this reason, I don't bother to weight it when I use it.  I just use 1/2 teaspoon per liter for 40ppm Colloidal Silver.

There is another DE number used, called %DE which is the reducing power of the molecule compared to glucose.
DE3 equals approximately a %DE of 33% to 39% depending on how the measurement was done.
DE6 equals approximately a %DE of 16% to 20% depending on how the measurement was done.
Normally the measurement is done by titrating a copper sulfate solution and the number depends on how pure the maltodextrin is (is it 100% the specified DE?)
94
Colloidal Silver Production / Re: availability of Soda and capping agents
« Last post by aquataur on March 19, 2024, 08:11:15 PM »
Thank you folks for donating your time to me. I well appreciate that. Our time is limited.

I have never heared those things about current and electrode size in my local "school of thought".
I think there is many things going wrong with that...

Thank god gave me the gift of being able to communicate with you in a common language (trade names and local customary names are excluded  :) ), so I can look over the pond.

Maybe I should briefly describe the local state of the art. This may be of interest for you.
You run with either 5 or 10 mA . Don´t know which and when. Heat pure DW to the boiling point but then no more. If possible, brew in a double walled glas to keep the heat. There is a magic ppm formula but this falls flat, because it assumes full current. Unfortunately current rises slowly until the current reduction kicks in, which may take several minutes. Sometimes cut-off is never reached even after hours. No stirring, no additives. There is some who use pulsed dc (a la zapper), some single polarity (which sometimes produces a yellow result), some switching polarity. It is left totally unclear which is better. Devices go up to 60V (which is the maximum allowable voltage for home use) to get things going at all. Single polarity produces black or grey sludge on the anode. Some devices use a cathode different than silver, but in this case it is not a bad thing to stay with both silver because people are bound to switch to alternating polarity without taking care of that.

There is one person who really understands the hardware side of it. His devices are unparalleld. But he seems to despise the "Boilers". He appears to be some kind of guru figure to the community.

Interestingly, all contact I tried to make with them was disabled by divine intervention. All things failed.

And then there is another guru who crowds disciples around him, who sells tinkerer´s boxes that contain nothing but a single resistor. The box is cheap, but not the electrodes made of unobtainium rare earths.

95
Colloidal Silver Production / Re: availability of Soda and capping agents
« Last post by kephra on March 19, 2024, 07:30:19 PM »
Aah! Instant enlightenment! That makes sense to me. The baylonian language confusion strikes again. Nobody would call it "baking soda" here. At least I have never consciously attributed the term to "Natron" as they call it here. In fact it is ubiquitous. I even have about 10kg of pristine powder in my shed. ;D
This does not happen for the first time that I cannot fathom what product Americans or English speak of until I realize, it is sitting right next to me, but with a totally different name.

I just realize that "eating soda" (obviously different to "washing soda", although very often used for cleaning purposes) is not commonly used for baking purposes hereabouts. I know that potassium carbonate is used for such purposes, but rarely.

Thank you again. This gets me going.
Right, sodium carbonate is not used for baking, but it is a result of baking, and you do consume it.  It is also used in commercial food preparation for adjusting pH.  It is also what gives pretzels the brown coating, as the dough is dipped into a solution of it before baking.

The language differences exist even between very similar cultures, like between the USA and Britain,
Most Americans do not know what bonnets and boots are with respect to cars.  We have hoods and trunks!
Most Americans do not know what Wellies and Macs are.  We have boots and raincoats.
Then there is metric versus imperial.
Everything in Britain is metric, except for beer which is still measured in pints.
In America most things are imperial except for spoons, soft drinks, automobiles, and medical equipment which are metric.
I'm sure there are other examples.
96
Colloidal Silver Production / Re: availability of Soda and capping agents
« Last post by Gene on March 19, 2024, 07:27:27 PM »
You can buy a box of sodium bicarbonate (baking soda) from most grocery stores in the US (1/2-1 pound box) for less than $1.  This, converted to sodium carbonate will yield you enough to last you probably half a millennium (wink).  Also, when converting sodium bicarbonate to sodium carbonate (by baking it at 350F+ in an oven for an hour), what you wind up with is anhydrous sodium carbonate. The mined, store-bought washing soda form has a few water molecules attached to each sodium carbonate molecule so necessarily, you use LESS of the anhydrous form than you would of the store-bought washing soda form. The correct amount of anhydrous is stated in the Kephra's Notebook section of the forum in one of the top pinned articles (I don't remember which one).

Given its anhydrous, if you produce your own, simply store it in a jar with a tight fitting lid to keep its exposure to moisture to a minimum. Sodium compounds are usually all slightly to some VERY hygroscopic (they absorb water from the air) which you'd want to endeavor to prevent if you intend to store the sodium carbonate you've produced for any length of time.

Regarding the current you're processing with, this is directly related to the surface area of the silver anode you're using. For wire anodes, perhaps even 5ma is too much. For silver bullion bar anodes (1oz troy), without stirring, you could probably push it up to 5-10ma, maybe 15ma with stirring.

To see if the current you're running at is too high, once you have your cell running, shine a flashlight through the cell and look at the area around the anode. If you see long whispy whafts of what resembles cigarette smoke leaving the anode, your current is too high. You need to back it down until they go away.

Patience is a virtue and with making Colloidal Silver by the electrolysis method, its a necessity. Production moves at a snails pace and you just have to bide your time to let it happen properly.

At room temp (this is stated as 75F cell temp, NOT 68F thats commonly referred to as room temp - at least in the US), the solubility limit of silver oxide in water is a mere 22PPM. Given this would indicate you're processing cold (Not heating the cell), the limit of production is the stated 20PPM. You NEVER want to push more silver ions into the water than the solubility limit because what exceeds the limit will precipitate out of solution and never reduce.  Given with cold processing you run the electrolysis to push the cell to the 20PPM ionic silver state where you then heat the cell and add the reducer AFTER the run, this dictates the 20PPM limit.

At 150F (usually where we process when making higher than 20PPM batches), the solubility limit is 40PPM. The trick with higher PPM production is to keep the speed of reduction (reducer MUST be added before the run) proceeding FASTER than the speed at which you're pushing silver ions into the water to keep the concentration of ionic silver in the water below 40PPM for the entire run. Also, when you reach the time limit, yeah, turn off the current but leave the cell on the hotplate for maybe another 10-15 minutes to make sure the silver oxide you pushed into the water for the last 10-15 minutes of the run actually reduces.  Having said this, generally the volume of water in the cell is sufficient to hold the cell temp above about 140F for more than enough time if even its removed from the hotplate but the way I look at it is that I'm in no rush and I have plenty of other things to do after a run (cleaning things,...) so I do that first before removing the cell from the hotplate. To each his own.

Its not rocket science but its not always obvious either.
97
Colloidal Silver Production / Re: maltrodextrin powder
« Last post by aquataur on March 19, 2024, 06:41:10 PM »
My question fits here nicely.

Since most of the syrup brands mentioned are not (readily) available in Austria, I checked maltodextrin.
That´s where the next headache starts. They offer three categories:

Quote
Maltodextrin 6, maltodextrin 12 and maltodextrin 19 are sold commercially. The individual products differ in the chain length of their sugar molecules. Maltodextrin 6, for example, has more longer-chain carbohydrates than maltodextrin 12 and 19. The chain length also influences the sweetness of maltodextrin: maltodextrin 6 is less sweet than maltodextrin 12 and 19.
(from a health site, translation by Deepl)

I see you guys have no choice regarding the DE values, but since we have, we might as well choose.
Which of those would support our reducing task better? (I have to admit that I don´t understand all of things chemistry).

Thanks.
98
Colloidal Silver Production / Re: availability of Soda and capping agents
« Last post by aquataur on March 19, 2024, 03:18:08 PM »
Whoever you have bee listening to does not know what they are talking about.
it looks like

This also tells me that your generator is useless for making quality colloidal silver.
I modified it so that it can be  just a 60V source with 5/10 mA current limiting.

Baking powder is not baking soda, also called bicarbonate of soda.  Baking soda is pure sodium bicarbonate, and I can't imagine a country that does not have it available.

Aah! Instant enlightenment! That makes sense to me. The baylonian language confusion strikes again. Nobody would call it "baking soda" here. At least I have never consciously attributed the term to "Natron" as they call it here. In fact it is ubiquitous. I even have about 10kg of pristine powder in my shed. ;D
This does not happen for the first time that I cannot fathom what product Americans or English speak of until I realize, it is sitting right next to me, but with a totally different name.

I just realize that "eating soda" (obviously different to "washing soda", although very often used for cleaning purposes) is not commonly used for baking purposes hereabouts. I know that potassium carbonate is used for such purposes, but rarely.

Thank you again. This gets me going.
99
Colloidal Silver Production / Re: availability of Soda and capping agents
« Last post by kephra on March 19, 2024, 12:01:22 PM »
Thank you for your reply. Makes sense what you say about moving silver between the electrodes. In fact the local consensus is (can you call it "consensus" if nobody has an explanation?) that it is not known why there is no sludge build-up at the cathode and what and if there is a difference between a clear and a yellow ahem liquid.
Whoever you have bee listening to does not know what they are talking about.
Quote
Indeed, the product I gain from this mode tastes very metallic and has a strong Tyndall effect - which is supposed to be "good",  until I learned more here. Also, there is a considerable dark fall-out.
So what you made is overcooked ionic silver, the kind that turns people blue.  This also tells me that your generator is useless for making quality colloidal silver.
Quote
@ baking powder: I looked up what the local baking powders are made of.

They usually consist of one or more carbonates an/or bicarbonates, acid salts like disodium hydrogen phosphate or potassium acid tartrate. Plus starch or oats fibers up to 65% as bulk agent. Sometimes they contain  lemon extract for taste and acidifying and artificial vanilla.

Eminently acceptable for a cake, but for making Colloidal Silver? I`ll rather get some carbonate from a chemistry dealer and be on the safe side. They have it 99,7% pure. Ironically, this is far cheaper than getting the small envelopes in the supermarket.
Baking powder is not baking soda, also called bicarbonate of soda.  Baking soda is pure sodium bicarbonate, and I can't imagine a country that does not have it available.  Baking powder is not good because of the other ingredient in it.
When a cake with baking soda is baked, the baking soda turns into washing soda (sodium carbonate), and if you have ever eaten cake, you have consumed washing soda.
100
Colloidal Silver Production / Re: availability of Soda and capping agents
« Last post by aquataur on March 19, 2024, 07:42:20 AM »
Thank you for your reply. Makes sense what you say about moving silver between the electrodes. In fact the local consensus is (can you call it "consensus" if nobody has an explanation?) that it is not known why there is no sludge build-up at the cathode and what and if there is a difference between a clear and a yellow ahem liquid.

Indeed, the product I gain from this mode tastes very metallic and has a strong Tyndall effect - which is supposed to be "good",  until I learned more here. Also, there is a considerable dark fall-out.

@ baking powder: I looked up what the local baking powders are made of.

They usually consist of one or more carbonates an/or bicarbonates, acid salts like disodium hydrogen phosphate or potassium acid tartrate. Plus starch or oats fibers up to 65% as bulk agent. Sometimes they contain  lemon extract for taste and acidifying and artificial vanilla.

Eminently acceptable for a cake, but for making Colloidal Silver? I`ll rather get some carbonate from a chemistry dealer and be on the safe side. They have it 99,7% pure. Ironically, this is far cheaper than getting the small envelopes in the supermarket.

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