Interesting question.
If you are using constant current/hot water/salt, then pH7 is perfect, as you will be creating sodium hydroxide which raises the pH of the water.
If you use sodium hydroxide as the initial electrolyte, then it will be slightly above pH7 at the start, but again it will climb some.
There is no point in starting with a pH below 7, as the sugar based reducing agents (maltodextrin, corn sugar, invert sugar) need to be in a solution which is basic, above pH7.
The point is though that the solution is going to change from the electrolysis producing sodium hydroxide, and probably gluconic acid if you add corn syrup at the start.
So I would say, pH7 is an ideal starting point.